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There has never been an emperor of Europe. There have been emperors of European countries/empires, but not of Europe itself.
the Spanish
english
Spain
European countries
Britain and other European countries.
Britain, France, America, all the new countries made from the German, Austro-Hungarian, Ottoman Empires.
What did the first Spanish settlers in the West build there?
Countries evolved from kingdoms and empires, so it would depend upon your def of "country."
The first two countries that claimed Latin America were France and Portugal
France
Portugal