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Its mainly going to be Hydrogen nuclii. At the suns core, two protons fuse together (hydrogen atom nuclei) to form deuterium. These in turn may fuse with further protons, or with another deuterium nuclei to for a helium nuclei. As the heavier nuclei form, energy is released.

Later on in the Stars life, fusion of the helium nuclii may take place a lot more often, as the preferred fuel of Hydrogen is depleted.

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