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The main property of a substance that make it either conduct or insulate is electro-negativity. Electro-negativity is a substances "willingness," so to speak, to give up electrons. Most transition metals have high electro-negativity, and thus conduct well. Another thing about all metals that make them conductive is the way their atoms interact. Metallic atoms engage in metallic bonding which is where a group of metal atoms lump together and form sort of a giant atom with the nuclei (separated) in the middle, and all the electrons speeding about on the outside.

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