Steptoe and Son - 1962 The Bond That Binds Us 3-6 is rated/received certificates of: UK:PG (video rating) (1995)
James Bond 007 From Russia with Love - 2005 VG is rated/received certificates of: Australia:M France:-12 Germany:16 Japan:15 Japan:R-15 UK:12 USA:T
Although it is difficult to discover which James Bond film was the first to be released on DVD, it is certain that they all have been. The newest James Bond movie, "Skyfall", was released on February 12, 2013 on DVD.
The James Bond film Skyfall (2012) is set for release on Blu-ray and DVD on February 12th, 2013.
I don't believe there were movie ratings when Goldfinger was released in 1964, but today the film (since it is James Bond movie) would likely be rated for Adult audiences.
Anna Bond - 2012 is rated/received certificates of: India:U/A
Boricua's Bond - 2000 is rated/received certificates of: USA:R
The Blood Bond - 2010 is rated/received certificates of: Germany:16
The Tailor of Bond Street - 1916 is rated/received certificates of: UK:U
The Many Faces of Bond - 1989 V is rated/received certificates of: UK:E
Ek Rishtaa The Bond of Love - 2001 is rated/received certificates of: Malaysia:U
The World of James Bond - 1995 TV is rated/received certificates of: USA:G
Tough Bond - 2013 was released on: Germany: 13 February 2013 (Berlin International Film Festival) Canada: 26 April 2013 (Hot Docs International Documentary Festival) USA: 11 October 2013 (Chicago International Film Festival)
Bond of Silence - 2010 TV is rated/received certificates of: Netherlands:12 USA:TV-PG
Best Ever Bond - 2002 TV is rated/received certificates of: Australia:PG UK:12
James Bond Casino - 2006 TV is rated/received certificates of: Netherlands:6 (original rating)
Fatal Bond - 1991 is rated/received certificates of: Argentina:13 Australia:M Germany:16 Iceland:16 USA:R