Fantastic Four - 1994 The Origin of the Fantastic Four Part 1 1-1 was released on:
USA: 24 September 1994
The Wonderful World of Disney 40 Years of Television Magic - 1994 TV was released on: USA: 10 December 1994
Star Trek Deep Space Nine - 1993 The Abandoned 3-6 was released on: USA: 31 October 1994
Star Trek The Next Generation - 1987 The Hunted 3-11 was released on: USA: 6 January 1990 Netherlands: 7 August 1994
Star Trek The Next Generation - 1987 Qpid 4-20 was released on: USA: 20 April 1991 UK: 2 November 1994
I believe the episode you are looking for is episode 'Arrival' from the 1994 'Spider-Man' cartoon. It is season 5, episode 9, and you can watch it on YouTube.
Fantastic Four - 1994 Superskrull - 1.7 was released on: USA: 5 November 1994
Fantastic Four - 1994 Incursion of the Skrulls 1-4 was released on: USA: 15 October 1994
Fantastic Four - 1994 Doomsday 2-13 was released on: USA: 24 February 1996
Fantastic Four - 1994 Behold the Negative Zone 1-12 was released on: USA: 10 December 1994
Fantastic Four - 1994 When Calls Galactus 2-8 was released on: USA: 18 November 1995
Fantastic Four - 1994 The Sentry Sinister 2-12 was released on: USA: 17 February 1996
Fantastic Four - 1994 The Mask of Doom Part 1 1-8 was released on: USA: 12 November 1994
Fantastic Four - 1994 The Mask of Doom Part 2 1-9 was released on: USA: 19 November 1994
Fantastic Four - 1994 To Battle the Living Planet 2-6 was released on: USA: 4 November 1995
Fantastic Four - 1994 Worlds Within Worlds 2-5 was released on: USA: 21 October 1995
Fantastic Four - 1994 Prey of the Black Panther 2-7 was released on: USA: 11 November 1995
Iron Man - 1994 Origin of the Mandarin 1-7 was released on: USA: 5 November 1994