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Lamens Terms: Because it is cold and like a cold glass of tea on a hot summer day, the moisture in the air condensates on the cold surface.

Technical: Because the surface of the duct is below the dew point temperature of the ambient air surrounding it, causing an accumulation of condensation on the surface itself. The room needs to be conditioned closer to the relative temperature of the air inside the duct (Usually with 15-25 degrees) to avoid the laws of enthalpy from taking place.

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