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Because atoms have negatively charged electrons orbiting the outside of them, atoms will repel each other. This means that it is extremely rare for atoms to collide, but when they do, the reaction depends on why it happened. If they are in a star for example, and the huge gravity and heat of the star forces them together, any atom lighter than iron will undergo fusion and make a heavier element. In fission reactors, it is extremely rare for an atom to hit another atom, but it can happen. Most of the time they will simply be hit by a flying electron before they can fuse, but even if they weren't, the atoms used in a fission reactor are much much heavier than iron and will not undergo fusion. The reason iron and anything heavier than iron cannot undergo fusion is that iron will absorb a huge amount of energy before it will fuse. In stars, the most powerful stable fusion reactors we know of, the iron will actually absorb so much energy that it kills the star. This is why stars will collapse after a short amount of time as a supernova. The supernova has layers with heavier and heavier atoms. When it reaches a layer with iron, it suddenly loses large amounts of energy and loses the ability to counteract gravity. This causes it to collapse into a dwarf star, or explode.

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