"UN/NA numbers (the four digit number) found on bulk placards refer to specific chemicals or groups of chemicals and are assigned by the United Nations and/or the United States Department of Transportation." from http://environmentalchemistry.com/yogi/hazmat/placards/
Link also has a way to look up the numbers to find out what the cargo is. List is way too long to get into here.
self heating or pyrophoric materials
It is a DOT hazardous materials placard indicating compressed oxygen.
Explosives
This is the UN Identification Number.
The word placard (noun meaning a sign, a notice, an advertisement) has no direct antonym; the closest would be 'without placard' or 'placard-less'.
The placard on the wall displayed the museum's latest exhibition information.
symbol, UN hazard class number, color, UN identification number
The number 4 on the NFPA 704 placard indicates the highest hazard in any of the three categories (health, fire, reactivity).
In French, "placard" is masculine.
the placard have been posted everywhere.
electronic safety
placard means a poster for public display. Example: there was no placard outside.