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When soap is used with hard water, a scum is formed and it;

  1. Might damage the fabric.
  2. Makes the need of more soap for cleaning.

One of the reactions involved in forming the scum is;

2 C17H35CO2-Na+(aq) + Ca2+(aq) --> Ca(C17H35CO2)2(s) + 2 Na2+(aq)

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