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Several things evaporate: the first is methanol, a toxic form of alcohol. Distillers throw this "first run" out. At a slightly higher temperature, ethanol will evaporate. Once condensed, that is the liquid which we all know as drinkable alcohol. Depending on the temperature of the distiller's still, water will evaporate next. After that, processing and ingredients determine the type of liquor made.

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Q: What evaporates in alcohol distillation?
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How is distillation used to make alcohol pure?

Alcohol has a lower boiling point than water, so it can be condensed separately out of an aqueous solution. When it evaporates, alcohol is removed directly from solutions that contain solid impurities.


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