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That would be oxygen.

Photosynthesis:

6CO2 + 6H20 --> C6H12O6 + 6O2

Respiration:

C6H12O6 + 6O2 --> 6CO2 + 6H2O

O2 is oxygen, H2O is water, CO2 is carbon dioxide

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Q: What gaseous substance that is a reactant of respiration is a product of photosynthesis?
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