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For a pure semiconductor:

The requirement for a semiconductor is that there is a small energy gap between electrons in their ground state and in an excited "band" of energy levels. A material is considered a semiconductor when the energy gap is approximately equal to the boltzmann constant multiplied by the temperature. (kT)

Therefore it is difficult to say a general rule as to what group would give semiconductors as this would take a much more in depth analysis of the energy levels. For example, in group 14, silicon is a well known semiconductor, however Germanium is verging on semi metal, and tin and lead are clearly metals.

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Q: What group contains elements that are often used as semiconductors?
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