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When salt water evaporates, the water becomes vapor but the salt remains behind. The water gets saltier and harder to evaporate, but finally only salt and any other solutes will be left behind.

Salt is chemically NaCl which is a solid. It is highly soluble in water because of the ionization of Na ions and Cl ions. When a salt solution is heated the water will evaporate and solid crystals of the NaCl will left behind.

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