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Particles are held together by inter-particular forces. Above absolute zero, 0K all particles have energy. The energy can be vibrational as in solids, and rotational and translational kinetic energy. As the temperature increases the vibrational energy increases to such a point that the inter-particular forces are broken. The solid then usually turns to liquid as it loses its structure and then eventually a gas. Some solids can sublimate ie turn directly to a gas and omit the liquid phase.

Example:

Water molecules, H2O are held together by polar forces called "hydrogen bonding". The slightly positive hydrogens are attracted to the negative oxygens of neighbouring molecules. That is why water is a liquid at room temperature despite the small size of the molecule. Heating the water allows the molecules to vibrate breaking the hydrogen bonding. At around 100 oC all of the bonds have enough energy to break and the liquid turns to a gas.

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