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In most cases, density decreases when energy in the form of heat increases. This is why bridges and concrete sidewalks require expansion joints to prevent cracking on a warm day, for example. On the contrary, when heat energy is removed from water to it's freezing point, the density decreases when it becomes a solid (ice) as the water molecules form a solid structure that separates them by a greater distance than liquid water. This is why ice floats on water.

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