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The air inside the balloon will contract as it cools, so the balloon will become smaller. The freezing process could affect the balloon's skin, making it brittle and liable to fracture.
The pressure on the rubber.
That would depend on whether the balloon was empty, full of air or full of water and as you have not told us which we can not help you. When asking questions please make them specific if you want us to help.
The gas molecules slow down and the water vapor condenses causing the balloon to shrink.
The Balloon Pops
It Freezes ! :P
The air inside the balloon will contract, so the balloon will tend to look slightly crinkled.
it gets hard as a rock
The air inside the balloon will contract as it cools, so the balloon will become smaller. The freezing process could affect the balloon's skin, making it brittle and liable to fracture.
Charles Law - the expansion (when heated) or contraction (when cooled) of gases. E.g. when you leave a balloon outside in the heat it will pop from the gas inside expanded, but when you put it in a freezer it will shrink as the gas inside contracts.
The balloon would shrink because the average kinetic energy of the gas molecules in the balloon decreases when the temperate decreases. Go and try it is a pretty fun!
It will burst! because of the pressure in the freezer.
The low temperature inside the freezer causes the air inside the balloon to contract.
They will start to thaw.
the balloon will inflate
I balloon will deflate. If you take it out of the freezer, give it some time and it will expand to normal.
The pressure on the rubber.