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A situation similar to this could be found in the "Legion of Superheroes" series, where a younger Superman (Superboy) has tiny kryptonite pieces blown onto him by a fellow Legionnaire under the influence of a terrible mystical force. Superman is rendered unable to move and has difficulty breathing. It is hinted that if left alone with these pieces, he will die. He somehow summons up one final breath to suck the kryptonite pieces into his mouth so he can spit them out with the last of his energy before taking a while to recuperate and re-capture the enchanted Legionnaire.

Therefore, if King Kong broke all the kryptonite into a million tiny pieces and then blew them all on Superman, they would affect and weaken Superman, because Superman has a reaction to kryptonite no matter the size (see another Legion of Superheroes issue where a tiny speck of dust is placed in Superman's brain and has an effect).

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