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Obsidian is volcanic glass that is formed naturally and found in certain parts of the world. It can be "chipped" like flint into arrow points and other shapes and when chipped it has extremely sharp edges.

A few tribes certainly made their arrowheads of obsidian, but it was not widely available; in his 1989 study of "Bows and Arrows of the Native Americans", Jim Hamm lists the types of points used in the area that became the USA; obsidian only occurs in the Great Basin of the south-west and on the west coast.

It was also used by the Aztecs and other Mexican tribes.

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