A representative particle is thought of as the smallest unit into which a substance may be divided without changing its composition. Some examples might be helpful. For a given chemical element, it's an atom. An atom of carbon is the smallest unit of carbon one can find.
For covalently bonded compounds & diatomic molecules, the representative particle is a molecule. For example, an atom of hydrogen and an atom chlorine covalently bond to make a molecule of hydrochloric acid (HCl), and that's the smallest unit of this compound that there is. Because a molecule is a group of 2 or more atoms covalently bonded together, the smallest particles of ionic compounds are the respective ions. For example the smallest particle of the ionic compound sodium chloride (NaCl, or table salt) is a sodium ion (Na+) and a chlorine ion (Cl-).
There is a "scaled up" application in physics and engineering, and it might apply to something like a grain of wheat being the representative particle of that grain crop. A kernel of corn might be the representative particle for that grain crop. A grain of salt might be the representative particle for granular salt as a market commodity. These are important because of considerations regarding density and "close packing" and "voids" in bulk quantities of each commodity. There are more examples of the application of the term if one looks.
A given size granule of an aggregate might be the representative particle for analysis in something like moisture penetration in sand, small pebbles, or chunks of rock.
On the other end of the scale, there are representative particles for certain applications in the physics lab where something like the characteristics of a particle beam may be under consideration. A certain particle of given mass and energy might be the representative particle for, say, the study of particle beam divergence.
Most applications for the student will be in chemistry, and that's where the atom, molecule or, possibly, the ion, will be shown to be the representative particles of an element, a compound, or an electrolytic solution respectively.
A molecule is the representative particle of a molecular compound. Molecules don't have representative particles, they are one.
The term for the simplest representative particle in a compound composed of nonmetal atoms is a molecule. A molecule consists of two or more nonmetal atoms chemically bonded together.
Potassium Nitrate is a compound. The transition metals are found in groups 4-12 of the Periodic Table
An Alpha particle
Usually that's a covalent compound, and the representative particle is called a molecule.
The representative particle for iodine is the iodine atom (I).
A molecule of potassium permanganate, KMnO4.
A molecule is the representative particle of a molecular compound. Molecules don't have representative particles, they are one.
A molecule, SO2
The representative particle of a sodium ion is Na⁺, which has lost one electron to become positively charged.
atom
A water molecule (H2O) contain two hydrogen atoms.
The term for the simplest representative particle in a compound composed of nonmetal atoms is a molecule. A molecule consists of two or more nonmetal atoms chemically bonded together.
Potassium Nitrate is a compound. The transition metals are found in groups 4-12 of the Periodic Table
Potassium-40 decays by emitting a beta particle, which is an electron. This decay process transforms potassium-40 into calcium-40.
The smallest representative particle for a compound like H2O (water) is a molecule, which consists of two hydrogen atoms bonded to one oxygen atom.
If you think to formula unit this is Na2S.