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What is a volhard method?

Updated: 9/18/2023
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11y ago

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It is an indirect titration procedure for the determination of anions that precipitate with silver like CL-, Br-, I-, SCN-, and it is preferred in acid (HNO3) solution (because it prevents the harmful effects seen in other methods in which oxalate, arsenate and carbonate are used. Because these ions form silver salts with poor solubility, but in acidic mediums these salts are not formed). A measured excess of AgNO3 is added to precipitate the anion, and the excess of Ag+ is determined by back titration with standard potassium thiocyanate solution.

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Q: What is a volhard method?
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