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Nitrobenzene is used in Volhard's method as a solvent because it is a non-polar, aprotic solvent that effectively dissolves a wide range of organic compounds. Its stability under acidic conditions allows it to facilitate the reaction without interfering with the titration process. Additionally, nitrobenzene's high boiling point enables the method to be conducted at elevated temperatures, which can enhance the reaction rates and improve the accuracy of the titration results.

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