fluff, fief
A five (5) letter word that starts with Z and ends with F, there is none recorded. However, there is a word that starts with Z and ends with F. The word is a four (4) letter word: zarf, (noun) a metal holder for a coffee cup.
A frog.
Fireproof Foolproof
facialfactualfailfaithfulfallfanaticalfancifulfarewellfastballfatalfatefulfearfulfeelfellfennelfetalfictionalfillfinalfinancialfingernailfistfulflannelfloralfocalfoilfoolfootballfoothillfootstoolforcefulforgetfulformalfossilfoulfowlfractionalfrailfreewillfrightfulfrillfrontalfrugalfruitfulfuelfullfunctionalfundamentalfuneralfunnel
zeefe
fine wine
fernando?
fishes
falloff
Firehose
Forgive
forsho