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What is an anharmonicity?

Bobo192 ∙

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∙ 11y ago

Updated: 8/21/2019

An anharmonicity is of or pertaining to the deviation of a system from harmonicity.

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∙ 11y ago

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What is electrical anharmonicity?

Electrical anharmonicity refers to a term in the potential energy of a crystal which is linear in the externally applied electric field amplitude, and quadratic in lattice displacement coordinates. As such, it gives a dielectric polariztion which is quadratic in the lattice coordinates. Such an interaction term of lattice and external field allows the direct absorption of photons by two-phonon states of the crystal.

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