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Charizard does not exactly have a "best attack." Depending on if you build it to deal physical or special damage the "best move" will change. Obviously if Charizard is built for special attacks a move like Fire Blast or Fly will deal optimum damage. For physical a more powerful attack like Take Down may be your choice.
i think its flamefrower
maybe even overheat (in TM)
or flame blitz
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