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what is colour of Mg2plus- EDTA complex?
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Why is the pH of the medium is important in EDTA titration?
pH must be constant by use of a buffer solution. Control of pH is important since the H+ ion plays an important role in chelation. Equation below shows complexation between metal ion and H+ ions for ligand:Thus and as mentioned before, stability of metal complex is pH dependent. Lower the pH of the solution, lesser would be the stability of complex (because more H+ ions are available to compete with the metal ions for ligand). Only metals that form very stable complexes can be titrated in acidic solution, and metals forming weak complexes can only be effectively titrated in alkaline solution. colour change of the indicator as well as the colour of the EDTA alos depend on the pH of themedium Therefor in EDTA tirtrations the pH of themedium is important :)
How do you use EDTA?
There are many different uses of EDTA. It is used to sequester metal ions in aqueous solutions and it helps prevent impurities in metal ions. Its main use is to treat mercury and lead poisoning in humans.
What is the purpose of an auxiliary complexing agent in an EDTA titration of a metal ion?
The purpose is for the agent to "bind to a metal strongly enough to prevent metal hydroxide from precipitating, but weakly enough to give up the metal when EDTA is added." -Quantitative Chemical Analysis, 8th edition, Daniel C. Harris
What is EDTA Chelation?
Chelation is the process of binding an atom or ion with a chemical compound so that the atom or ion can remain soluble and loses its chemical reactivity. EDTA (ethylenediaminetetraacetic acid) is one well know chelating compound. Its structure allows it to bind to metal ions, usually with 2 or 3 EDTA molecules bound to one metal ion. By binding to and surrounding a metal ion, EDTA keeps the metal ion soluble and isolated from other ions that it might normally react with.
Are ligands complex ions?
A ligand is only a part of a metal complex.
What are different types of EDTA titration?
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
Why is magnesium sulphate added in the assay of calcium lactate?
Replacement Titration: In this method the metal, which is to be analyzed, displaces quantitatively the metal from the complex. When direct or back titrations do not give sharp end points, the metal may be determined by the displacement of an equivalent amount of Mg or Zn from a less stable EDTA complex. Mn+2 + Mg EDTA---> 2 Mg+2 + Mn EDTA-2 Mn displaces Mg from Mn EDTA solution. The freed Mg metal is then directly titrated with a standard EDTA solution. In this method, excess quantity of Mg EDTA chelate is added to Mn solution. Mn quantitatively displaces Mg from Mg EDTA chelate. This displacement takes place because Mn forms a more stable complex with EDTA. By this method Ca, Pb, Hg may be determined using Eriochrome blackT indicator.
Why is disodium salt of EDTA preferred to EDTA?
because edta has four active sites. therefore disodium salt of edta has 2 active sites that form soluble complex with the divalent metal ions
Why are indicators in complexometric titration added in a solid form?
Indicator is added to zinc because firstly it combines with zinc and forms zinc-indicator complex and after addition of more EDTA to the complex , the zinc which was in the form of complex gave free indicator and forms Zn-EDTA complex and the free indicator gaves blue colour which indicates end point of titration.
What causes the colour of complex ions?
Transition metal ions
What is the purpose of standardizing EDTA in Complexometric titration?
we standardize edta to make the soln stable complex
Why is the pH of the medium is important in EDTA titration?
pH must be constant by use of a buffer solution. Control of pH is important since the H+ ion plays an important role in chelation. Equation below shows complexation between metal ion and H+ ions for ligand:Thus and as mentioned before, stability of metal complex is pH dependent. Lower the pH of the solution, lesser would be the stability of complex (because more H+ ions are available to compete with the metal ions for ligand). Only metals that form very stable complexes can be titrated in acidic solution, and metals forming weak complexes can only be effectively titrated in alkaline solution. colour change of the indicator as well as the colour of the EDTA alos depend on the pH of themedium Therefor in EDTA tirtrations the pH of themedium is important :)
What is the function of EDTA in the motility medium?
EDTA is known to be used in mixtures where metal ions are present. So to avoid these metal ions from binding to the other components, EDTA is added to bind them and thus chelation takes place. Metal ions are known to bind to the flagella of bacterial cells.
What are the applications of complexometric titration?
The Applications of Complexometric Titrations are as follows:1. Direct Titration: It is the simplest and the most convenient method in which thestandard solution of EDTA is slowly added to the metal ion solution till the endpoint is achieved. It is similar to simple acid-base titrations. For this method tobe useful the formation constant must be large and the indicator must provide avery distinct color change as mentioned earlier. Further we need standardizedsolution of EDTA and sometimes auxiliary complexing agents may be required.Some important elements which could be determined directly by thecomplexometric titration are Cu, Mn, Ca, Ba, Br, Zn, Cd, Hg, Al, Sn, Pb, Bi, Cr,Mo, Fe, Co, Ni, and Pd, etc. However, the presence of other ions may causeinterference and need to be suitably handled.2. Back Titration: In this method, an excess of a standard solution of EDTA isadded to the metal solution being determined so as to complex all the metal ionspresent in the solution. The excess of EDTA left after the complex formationwith the metal is back titrated with a standard solution of a second metal ion.This method becomes necessary if the analyte precipitates in the absence ofEDTA or reacts too slowly with EDTA, or it blocks the indicator. For example,determination of Mn is done by this method because a direct titration is notpossible due to precipitation of Mn (OH)2. The excess EDTA remaining aftercomplexation, is back titrated with a standard Zn solution using Eriochromeblack T as indicator. However, one has to ensure the standard metal ion shouldnot displace the analyte ion from their EDTA complex.3. Replacement Titration: When direct or back titrations do not give sharp endpoints or when there is no suitable indicator for the analyte the metal may bedetermined by this method. The metal to be analyzed is added to a metal-EDTAcomplex. The analyte ion (with higher Kf′) displaces EDTA from the metal andthe metal is subsequently titrated with standard EDTA. For example, in thedetermination of Mn an excess of Mg EDTA chelate is added to Mn solution.The Mn ions quantitatively displace Mg from Mg-EDTA solution because Mnforms a more stable complex with EDTA.Mn+ + MgY2 - (MY)(n - 4)+ + Mg2+The freed Mg metal is then directly titrated with a standard solution of EDTAusing Eriochrome black T indicator. Ca, Pb and Hg may also be determined bythis method.4. Indirect Titration: Certain anions that form precipitate with metal cations anddo not react with EDTA can be analyzed indirectly. The anion is firstprecipitated with a metal cation and the precipitate is washed and boiled with anexcess of disodium EDTA solution to form the metal complex.Mn+ + H2Y2 - (MY)(n - 4)+ + 2H+The protons from disodium EDTA are displaced by a heavy metal and titratedwith sodium alkali. Therefore, this method is also called alkalimetric titration.For example, barbiturates can be determined by this method.
Determination of fe3 with EDTA by photometric titration?
Iron (III) ions form a deep-coloured complex with a maximum absorption at about 525nm; this complex is used as the basis for the photometric titration of iron(III) ion with standard EDTA solution.
How do you use EDTA?
There are many different uses of EDTA. It is used to sequester metal ions in aqueous solutions and it helps prevent impurities in metal ions. Its main use is to treat mercury and lead poisoning in humans.
What is the purpose of an auxiliary complexing agent in an EDTA titration of a metal ion?
The purpose is for the agent to "bind to a metal strongly enough to prevent metal hydroxide from precipitating, but weakly enough to give up the metal when EDTA is added." -Quantitative Chemical Analysis, 8th edition, Daniel C. Harris
