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Statistical thermodynamics uses probability and probability distributions for large collections of particles to reproduce the same properties of macroscopic systems already established by classical thermodynamics. In so doing it can give insights into the why's of thermodynamics. Statistical thermodynamics can utilize the equations of quantum mechanics for interatomic and intermolecular forces to further explain the thermodynamic properties of macroscopic systems of real matter based on what is happening down at the atomic level.

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Q: What is statistical thermodynamics?
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