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Sterling normally refers to the metal silver. 14kt is normally referring to the purity of the precious metal Gold. I would guess that sterling 14kt could mean that its an item that is made of silver but is plated in a very thin layer of gold,as in 'Gold Plated' sometimes also called 'Silver Gilt'.Gold does not tarnish or react with chemicals or oxidise or rust so is often used to coat silver.
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