Raman scattering involves the SCATTERING of electromagnetic radiation by molecules, not atoms
Fluorescence emission follows an absorption process
In spectroscopy, active vibrations refer to those that cause a change in the dipole moment of a molecule, while Raman active vibrations cause a change in the polarizability of a molecule. Both types of vibrations can be observed in spectroscopy, but they have different effects on the properties of the molecule being studied.
Raman spectroscopy measures the scattering of light, while FTIR spectroscopy measures the absorption of infrared light. Raman spectroscopy is better for analyzing crystalline materials, while FTIR is more suitable for identifying functional groups in organic compounds. Additionally, Raman spectroscopy is less sensitive to water interference compared to FTIR spectroscopy.
The formula is: Wavelength of Stokes line = Wavelength of laser / (1 - wavenumber of Raman shift) Wavelength of anti-Stokes line = Wavelength of laser / (1 + wavenumber of Raman shift) Here, the wavenumber of the Raman shift is represented in reciprocal centimeters.
Metals have the ability to shield external electric field, therefore when laser light used for excitation in Raman spectroscopy falls on the metal surface, it cannot penetrate very deeply. Also, noble metals have crystal structures with only one atom per unit cell, therefore only acoustic phonons exist, and no optic phonons that could be detected with Raman. Exceptioon is gallium - see ref. J.A. Creighton and R. Withnall Chemical Physics Letters , volume 326 (2000) pages 311-313.
It depends what you are looking for. There are online databases of Raman spectra for minerals, for example, e.g. https://www.fis.unipr.it/phevix/ramandb.php For characteristic functional groups/molecules and their peaks, it is better to consult a textbook of Raman Spectra, within which you can find tables of peak assignments - take a visit to the library!
Raman Effect
The Raman effect was discovered by Indian physicist Sir C. V. Raman in 1928. Raman was awarded the Nobel Prize in Physics in 1930 for this discovery.
sir cv raman invented raman effect raman effect is a change in the wave length of light that occurs when a light beam is deflected by molecules. Raman effect states that when monochromatic light is passed through a substance it attains some additional frequencies other than its frequency .
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Raman effect is change in the wavelength of light that occurs when a light beam is deflected by molecules.
C.V.Raman
The Raman effect, also known as Raman scattering, is the inelastic scattering of a photon. It was discovered by C. V. Raman and K. S. Kishnan in liquids. G. Landsberg and L. I. Mandelstam discovered it in crystals.
C. V. Raman was awarded the Nobel Prize for his work on the scattering of light and for the discovery of the Raman effect.
1903-1909
C V Raman is best known for his invention of the Raman effect, which demonstrated the scattering of light by molecules. This discovery established the field of Raman spectroscopy, which is widely used in various scientific fields.
The Raman effect refers to the inelastic scattering of light by molecules, resulting in a change in energy of the scattered photons. This effect provides information about the vibrational and rotational modes of molecules, making it a useful tool for analyzing chemical structures and compositions. Raman spectroscopy is a common technique that utilizes the Raman effect for various applications in chemistry, physics, and materials science.
raman effect states that when a monochromatic light is passed through a substance,it attains some additional frequencies other than its incident frequency.