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The electron configuration of Polonium, atom number 84, is:

In shells n=1 to 6:

2, 8, 18, 32, 18, 6

In subshells:

1s2, 2s2 2p6, 3s2 3p6, 4s2 3d10 4p6, 5s2 4d10 5p6, 6s2 4f14 5d10 6p4

or in shorthand: [Xe] 6s2 4f14 5d10 6p4

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