In Generation V, the last move Chansey learns is Double-Edge at Level 54.
The last move Scolipede learns is double-edge, which it learns at level 55.
The last move that sceptile learns is leaf storm.
Charizard learns a rather disappointing move called Fire Spin as its last move. It learns this move at level 64
The last move Charizard learns is Flare Blitz at level 66...
The last move it learns is Outrage, at level 85
The last move, in fire red, that Charizard learns is Fire Spin. That is at Level 55.
the last move luxray knows is discharge
his/her last move is explosion at level 52
Thunder
the last move he learns is amnesia at LV 65
The last move that Growlithe learns is Flare Blitz at level 45. Growlithe also learns Outrage at level 43 which is useful again the Dragon type.
Gengar's last move is Nightmare, which it learns at level 55.