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phosphorus as well as the PIII oxidation state has an oxidation state of PV. Its the +5 oxidation state we need to bond 4 chlorines to phosphorus. So we also need another monovalent atom e.g. a halogen to balance up the oxidation state.

One possibility for a neutral compound would be a mixed halide e.g. FPCl4

This compound is known and is usually called phosphorus tetrachloride fluoride.

A cheeky answer would be PCl5 it has four chlorine atoms too!

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