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Firstly, remember that a large member of any series is likely to have a higher boiling point than a small member of another series. Given that we assume we are dealing with similar sized molecules, alkanes will have the lowest bp's, as the molecules are non polar so we have only van der Waals forces. Ketones will come next as the carbonyl group is polar so there will also be dipole-dipole interactions. Alcohols and carboxylic acids come next, in that order, as they also have hydrogen bonds.

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Q: What is the order according to increasing boiling point of ketones alcohols alkanes and carboxylic acid?
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