The song is called How soon is now by the smiths
There's been dispute on what the song/artist was in the beginning of that episode. It was speculated that it was "TwentyFourSeven" by Artful Dodger, but it has not been fully confirmed.
The song that plays is Prologue by Jeremy Zuckerman. The song is edited to fit the beginning.
if you get Shazam on your phone you can watch episode 33 and let it do all the work for you.
Goo goo dolls - sympathy
Magic in my Heart! And if your wondering it's in the episode called Magic in my Heart!
If you're referring to the episode, "Privilege", then the song playing at the beginning was "Pride" by Syntax.
Nine Inch Nails - Capital G
"the WORLD" by Nightmare .
Somewhere Over The Rainbow
it is by the sugababes
Queen
Could be Steve perry - strung out