Yes, it is correct.
If the sign of ΔH is _______ and the sign of ΔS is _______ , then the magnitude of TΔS must be ________ than the magnitude of ΔH for the reaction to be spontaneous. The Gibbs free energy equation is ΔG = ΔH - TΔS. negative; negative; less
spontaneous
Spontaneous
For some non-spontaneous reactions, you can change the temperature. For other non-spontaneous reactions, there is nothing you can do to make it spontaneous. Nature favors reactions that increase a system's entropy (disorder) and nature favors reactions that are exothermic (they release enthalpy). Any reaction that does both of these things is spontaneous at all temperatures. Any reaction that does neither of these things is never spontaneous. As far as this question is concerned, the interesting reactions are endothermic reactions that increase entropy and exothermic reactions that decrease entropy. Whether these reactions are spontaneous depends on the temperature. The first variety (endothermic, increase entropy) will be spontaneous at high temperatures; the second (exothermic, decrease entropy) will be spontaneous at low temperatures. To find the temperature at which a reaction becomes spontaneous, one may apply the Gibbs equation: DG = DH - TDS where capital Ds stand for the Greek capital delta.
All nuclear decay is spontaneous.
The reaction is spontaneous below 743 K.
The reaction is spontaneous below 554.8/0.1975 K.
The reaction is spontaneous above 371 K.
Yes, it is correct.
If by "real life" you include the physical world, then you express the spontaneous decay of radioactivity in a sample with a logarithmic equation.
-51 - -50.5
Reactions are described by this equation: GD = HD - TDS where D = delta for change in values. GD < 0 spontaneous HD < 0 exothermic ; HD > 0 endothermic The first equation is Gibbs free energy. When G is negative, the reaction is spontaneous. In contrast, a positive number G is non spontaneous. The interesting thing is that spontaneous reactions can be EITHER exothermic and endothermic. Lets look at this: lets assume HD has a value of 100. This means TDS would have to be bigger than 100 in order to make GD a negative number. An endothermic reaction which has a positive H can still be exothermic. Here's another way to pose your question: Is an exothermic reaction spontaneous? Always. Is an endothermic reaction spontaneous? This can be either.
when H is negative and S is positive
97.6 - 98
The equation for the alpha decay of 235U is: 92235U --> 90231Th + 24He representing the alpha particle as a helium nucleus. 235U also decays by spontaneous fission, but the results are somewhat unpredictable, so there is no standard equation.
methane+oxygen-->carbon dioxide+waste CH4 O2 CO2 H2O