Union is a noun.
There is no specific clause about labor unions in the Constitution. Yet, you could combine a couple of the civil liberties such as freedom of assembly and freedom of speech to support the concept of labor unions.
The part of speech for this particular word is a noun.
part of speech
The part of speech for "answer" is a noun.
what part of speech is beneath
adverb
The part of speech for "explicit" is an adjective.
The part of speech for "lecturer" is a noun.
The part of speech for "rapid" is an adjective.
The part of speech of "came" is a verb.
The part of speech for "breezy" is an adjective.
The part of speech for "buried" is a verb.