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I recommend saving it for mewtwo, in Cerulean cave.

It's a strong Pokemon, and has a high chance of defeating you and a low chance of capture, and you also have to take into concideration that the cave you need to travel through to reach it is very dangerous, with high-level Pokemon; needless to say, your Pokemon will be tired when you fight it.

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Q: What rare Pokemon should you catch with a master ball on fire red?
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