If you're interested in major cities that fall very close to that latitude, the best answers are Cordoba, Argentina and Porto Alegre, Brasil.
cape town, south Africa
Terrigal, New South Wales., Australia is the closest city at 33 degrees South 151 degrees East.
Charleston,South Carolina
The largest city closest to that point is Santiago, Chile which is just east of that point.
These coordinates are in the Indian Ocean, about 120 miles east of the city of Durban, South Africa.
Cape Town
Maricopa, Arizona, south of Phoenix.
Creighton, South Africa
what is capital of 33°S and 70°W
The whole point about 60 degrees south (Northern limit of the Southern Ocean) is that there is NO LAND anywhere on that latitude.
330 33' 33" N, 660 33' 33" N, 630 33' 33" S, and 330 33' 33" S BRUH33 degrees 33' 33" North, 66 degrees 33' 33", 63 degrees 33' 33" South and 33 degrees 33' 33" South
Cape Town is the legislative capital of the Republic of South Africa. Cape Town is located 33 degrees 56′S 18 degrees 25′E.