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Most reactions with KOH are in solution with water: acid-base reactions, only by the OH- ions:

(OH-)aq + (NH4+)aq --> (NH3)g + H2O

But also solid KOH could react e.g. with CO2:

2KOH + CO2 --> K2CO3 + H2O

KOH doesn't exist (is not stable, decomposes) in gaseous state at high temperatures.

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