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There are a number of reasons a space shuttle doesn't explode when re-entering Earth's atmosphere.

First and foremost is the return trajectory. A shuttle angles upon return so that its descent is not too fast, preventing a majority of friction heat. Next, the entire shuttle is covered with a layer of heat-resistent ceramic panels that prevent the hull from being damaged. Next, there is usually a layer of high-grade industrial lubricant on the outer layer of panels (it used to be WD-40, but I think they've moved on since then).

Finally, the interior mechanisms of the shuttle are designed to prevent explosion should any of these failsafes...well...fail.

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15y ago

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