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When adding the aldehyde or ketone to Tollens' reagent, the test tube is put in a warm water bath. If the reactant under test is an aldehyde, Tollens' test results in a silver mirror. If the reactant is a ketone, it will not react because a ketone cannot be oxidized easily. A ketone has no available hydrogen atom on the carbonyl carbon that can be oxidized - unlike an aldehyde, which has this hydrogen atom.

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Why fructose gives positive tollen reagent test?

Only aldehydes give a positive Tollens test. However, under the strongly basic conditions of the test, alpha-hydroxy ketones can isomerize to aldehydes, so they will also give a positive Tollens test. Fructose is an alpha-hydroxy ketone.


Is vanillin positive in tollens test?

No.While vanillin is an aldehyde, which should react with Tollens' reagent to precipitate silver metal, vanillin does not "pass" Tollens' test. Tollens' reagent is very basic (sodium or potassium hydroxide). Vanillin has a phenolic hydrogen (OH bonded to a phenyl ring) which is slightly acidic. Vanillin will react first with the excess hydroxide ions in solution to form a phenoxide salt, which will not participate in the silver-precipitating reaction.


Will CH3CHO react to tollens?

Yes, CH3CHO (acetaldehyde) will react with Tollens' reagent. Tollens' reagent is commonly used to test for the presence of aldehydes, including acetaldehyde, by forming a silver mirror on the walls of the test tube when a positive result is obtained.


What is the mechanism of the Tollens test and how does it differentiate between aldehydes and ketones?

The Tollens test involves the oxidation of aldehydes to carboxylic acids by silver ions in a basic solution. This forms a silver mirror on the inside of the test tube. Ketones do not react with Tollens reagent and do not produce a silver mirror. This test is used to differentiate between aldehydes and ketones based on their reactivity with Tollens reagent.


What is the reaction of acetone and tollens reagent?

Acetone does not react with Tollens' reagent (ammoniacal silver nitrate solution) because it does not contain an aldehyde group, which is necessary for the Tollens' test to occur. Tollens' reagent reacts with aldehydes to produce a silver mirror on the inner surface of the test tube.

Related Questions

Is fructose gives positive test with tollens reagent?

Fructose does not give a positive test with Tollens' reagent because it is a reducing sugar that does not have a free aldehyde group capable of reducing the Tollens' reagent. Tollens' reagent is typically used to detect the presence of aldehydes but may not react with fructose due to its ketone functional group.


Why fructose gives positive tollen reagent test?

Only aldehydes give a positive Tollens test. However, under the strongly basic conditions of the test, alpha-hydroxy ketones can isomerize to aldehydes, so they will also give a positive Tollens test. Fructose is an alpha-hydroxy ketone.


How is a positive tollens test recognised?

A silverish ppt. Called "silver mirror"


What is the principles of tollen's test?

The principle of Tollens' test is to distinguish between aldehydes and ketones. It involves the reduction of silver ions to silver metal in the presence of aldehydes, which results in the formation of a silver mirror on the inner surface of the test tube. Ketones do not give a positive Tollens' test because they do not undergo this reaction with silver ions.


Are substances that test positive with the Ames test necessarily carciongenic in humans?

The substances that are test positive with Ames test may or may not be carcinogenic for humans. Similarly, some substances that cause cancer in laboratory animals do not give a positive result Ames test. It is not possible to decide the carcinogenicity of any substances only depending on the Ames test.


Is vanillin positive in tollens test?

No.While vanillin is an aldehyde, which should react with Tollens' reagent to precipitate silver metal, vanillin does not "pass" Tollens' test. Tollens' reagent is very basic (sodium or potassium hydroxide). Vanillin has a phenolic hydrogen (OH bonded to a phenyl ring) which is slightly acidic. Vanillin will react first with the excess hydroxide ions in solution to form a phenoxide salt, which will not participate in the silver-precipitating reaction.


Will CH3CHO react to tollens?

Yes, CH3CHO (acetaldehyde) will react with Tollens' reagent. Tollens' reagent is commonly used to test for the presence of aldehydes, including acetaldehyde, by forming a silver mirror on the walls of the test tube when a positive result is obtained.


Does the tollens test deal with alkenes?

No, the Tollen's Silver Mirror Test only confirms the presence of aldehydes.


What is the mechanism of the Tollens test and how does it differentiate between aldehydes and ketones?

The Tollens test involves the oxidation of aldehydes to carboxylic acids by silver ions in a basic solution. This forms a silver mirror on the inside of the test tube. Ketones do not react with Tollens reagent and do not produce a silver mirror. This test is used to differentiate between aldehydes and ketones based on their reactivity with Tollens reagent.


What is the reaction of acetone and tollens reagent?

Acetone does not react with Tollens' reagent (ammoniacal silver nitrate solution) because it does not contain an aldehyde group, which is necessary for the Tollens' test to occur. Tollens' reagent reacts with aldehydes to produce a silver mirror on the inner surface of the test tube.


Did gelatin give positive result with xanthoprotic test?

yes,it give positive test


Do Hydrocodone and Morphine give the same results on an urine test?

Yes the two substances will indicate a positive result for opioid ingestion.