Whig Party Presidential candidate William Henry Harrison and his Vice Presidential running mate John Tyler won the 1840 presidential election defeating Democratic Party incumbent President Martin Van Buren and his running mate Richard Johnson. In the 1840 presidential election there was a total of 294 electoral votes thereby requiring a majority of 148 votes to win the presidential election. William Henry Harrison and John Tyler received 234 electoral votes. Martin Van Buren and Richard Johnson received 60 electoral votes.
It Means that the Electoral College approves the vote
The electoral college does not vote on policies. The electoral college performs only one function. It elects the president of the United States.
The electoral college now reflects each state's popular vote.
It seems you are asking for 4 presidential elections in which the candidate who won the popular vote did not win the electoral college. Here are four such examples: 1824: Andrew Jackson won the popular vote but lost the electoral college to John Quincy Adams. 1876: Samuel J. Tilden won the popular vote but lost the electoral college to Rutherford B. Hayes. 1888: Grover Cleveland won the popular vote but lost the electoral college to Benjamin Harrison. 2000: Al Gore won the popular vote but lost the electoral college to George W. Bush.
The popular vote in each state selects the electors who will vote in the Electoral College. The electors are elected by popular vote in each state and each candidate for elector swears in advance whom he will vote for.
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Electors are elected by popular vote but the president is elected by the electoral college. A president candidate can win the popular vote and still not win if he doesn't win the electoral college.
There are no key dates. The electoral college votes after the popular vote.
John Quincy Adams was the only US president to be elected after losing the electoral vote. In 1824, no candidate won a majority of the electoral vote, so the election went to the House to decide. They chose Adams even though Andrew Jackson had won more electoral votes.
John Quincy Adams, in 1824.