Hot water is a weedkiller that can be used without harming the outside of a pool. Removal by gloved hand or by hoe or trowel function the best for weeds that are in physical contact with the pool sides. Clearing the ground of cover, placing black plastic sheeting over the bare soil, and weighting the solarization-serving sheeting down with garden or patio-style stones for walking on will keep weeds from establishing or returning.
Bugs, frogs, salamanders, tadpoles or any other bugs that are attracted to your swimming pool water will die when you super chlorinate or "shock" your pool. The Chlorine is used as a sanitizer will terminate the insects, ect. However, if you regularly net or skim your swimming pool surface water this will also remove them from the water without harming them. You will never be able to keep them from entering the water if it is a outdoor swimming pool. Hope this helps!!!
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