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An insulator does not generally hold a charge, in fact they resist the flow of electrons, this is what makes them insulators. In some cases though, you can build an electrical charge by rubbing a material (usually fibrous like carpet, wool or hair) with an insulator, though not all insulating materials under all conditions. Mostly this works in cold dry conditions because the air itself will act as an insulator not allowing the static electricity to dissipate through the atmosphere. This is why you get shocked in the winter more than in the summer when you grab a doorknob. As for the charge now accumulated on the insulator, think rubber balloon rubbed on hair, It will tend to stay there until it finds a path to ground. Then the charge will dissipated from the area surrounding the contact, but the areas further away may not dissipated because the electrons can not move across the insulator. To sum it up, the electrical charge will transfer to the conductor but an insulator will not charge under normal circumstances.

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Q: What will happen if you nearly touch charged insulator?
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