almighty
adultery
amnesty
alimony
uncommonlyuncertaintyuniformlyuglyunityuniversallyunusuallyunwillinglyusuallyuselesslyunconsciously
varyverifyvacancyvastlyviciouslyveterinaryversifyvitrifyvalleyvanityvarietyveryvictoryviceroyvisionaryvoluntaryvaguelyvolleyvalidityverbosityviscosityvoracityverityvarsityvelocityvelvety
yeahyouth
oy
baby
Acceptability, admissibility and affordability begin with a and end with y. Applicability, assignability and attainability begin with a and end with y.
There are words that end with z and begin with most letters. However, there are no words in the English language that begin with y and end with z.
harley
Berkley
vitaility??
Viscosity
There are hundreds of words end in ible and able. However, there are no words in the English language that begin with the letter y and end in ible or able.