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When water boils the gasses which where absorbed are liberated and they expand as a result of the heat causing bubbles which then rise to the surface upon further heating it would be the water turning to steam that expands into bubbles, that is why the bubbles only form at the point of contact with the heat source. there could be some oxygen in the bubbles but it would be extremely small amounts as the heat does not split the bond between the oxygen and the hydrogen.

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Q: When a jug boils there are large bubbles in the water What are the bubbles made of?
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