Pikachu starts out with thundershock when hatched from an egg, or caught in the wild. There is a 100% chance it will have thundershock if you catch it at level 25 or below in Pokemon Red/Blue, 10 or below in all Gen 2, and Gen 3 Pokemon games. Level 12 or below in Gen 4, and Gen 5 Pokemon games.
A pikachu can learn thundershock, growl,thunderwave, tail whip, quick attack, double team, slam, thunderbolt, agility, thunder, and light screen by itself.
he does not learn thundershock in any of the pokemon games.
Thundershock is not a move!!!!!!!!!!!!!!!!
No Yes, Pikachu can learn volt tackle! You need a Nincada in the front of your party (Migrate from Ruby/Sapphire/Emerald) and go catch a Pikachu. It should hold a light ball when you catch it, and must be a female. Then, breed it. You will then get an egg. It will hatch to a Pichu knowing Thundershock, Charm, and Volt Tackle.
ThunderShock
As of the Pokemon Diamond and Pearl games, Pikachu learn the following moves:Egg moves - Bide, Charge, Doubleslap, Encore, Fake Out, Present, Reversal, Thunderpunch, Tickle, Volt Tackle, WishPichu moves - Charm, Sweet Kiss, Nasty PlotStart moves - Thundershock, GrowlLevel 6 - Tail WhipLevel 10 - Thunder WaveLevel 13 - Quick AttackLevel 18 - Double TeamLevel 21 - SlamLevel 26 - ThunderboltLevel 29 - FeintLevel 34 - AgilityLevel 37 - DischargeLevel 42 - Light ScreenLevel 45 - ThunderPikachu will learn: thundershock, growl, thunder wave, quick attack, swift, agility, and thunder. Any other moves Pikachu is compatible with, may be learned by certain TM and/or HM moves.
Pikachu's move set in Pokemon X and Y includes Growl, ThunderShock, Tail Whip, and Thunder Wave.
in fushia city you have to get the gold theeth go to him (his house is close to the gym)i ment mr.figi sorry he will give it write next to you their will be a rock move you will have a rare candy you must have strength though
leveling up: thundershock growl tail whip thunder wave quick attack double team slam thunderbolt agility thunder light screen
Thunderbolt, thunderwave, thundershock, flash
Breed a Pikachu holding a Light Ball with a Raichu, Pichu, Pikachu, or Ditto. Hatch the egg to get a Pichu with Volt Tackle. Or, you could just beat all the Colosseum's in Pokemon Battle Revolution and send the reward (Surfing Pikachu) to your DS game. It is Lv.10 and its moves are: Surf, Volt Tackle, Thundershock, Tail Whip.
spark and thundershock are two good ones