Yes, when she did his homework for him. In the sixth book, I think (Harry Potter and the Half-Blood Prince).
The books suggest that Ron never really loved Lavender Brown, but instead loved Hermione.
Ron Weasley loved Hermione. Harry only loved her like a sister.
Because Hermione belongs 2 Ron and always has loved Ron not Harry
Hermione never told anybody, that she loves Ron, but she was jealous of Lavender Brown, bacause Ron was going out with her and kissing her.
Harry's relationship with Hermione and Ron was past favorites. He loved them both very much. They had become family to him.
Answer: Just so it should be a awkward moment...He loved her and He had a dream about her.
When Ron wore the locket he was tortured into believing Harry and Hermione loved each other. Harry told Ron that he had to be the one to destory it and when they opened it a Riddle-Harry & Riddle-Hermione emerged and showed Harry how Ron really felt. The Riddle-Harry & Riddle-Hermione told Ron that he was unimportant and kissed which gave Ron the power to stab it. Harry then tells Ron that Hermione is like his sister.
Hermione Granger gets in between Harry and Ron to prevent them from fighting with each other. Ron asks Hermione if she'll leave with him, but she refuses and he storms off. Hermione chased after him but he had already apparated away and due to their protective spells would be unable to find them again.
J.K.Rowling has stated many times that Harry and Hermione were never meant to be in a realtionship. In the final book she explains that Harry and Hermione are more like sisters. Hermione has always loved Ron and Harry has always loved Ginny.
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That Harry & Ron were sneaking out to the Trophy Room after hours to duel Malfoy.
Ron and Hermione are both to proud to admit they have feelings for each other and they fight more and more