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Generally when temperature increases, resistance increases and conduction decreases in metals. In semiconductors, this is generally inverted.

First, when temperature increases, the molecular activity of the material increases, making the energy (and activity) of the atoms to be higher. This can make it more difficult for the electrons to participate in the cascade effect that we call electric current, hence increased resistance.

Second, conductance is defined as the inverse of resistance; if resistance goes up, then conductance goes down, and vice versa.

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