If you're talking about Pokemon Pearl, in the beginning of the game, there is a piplup, chimchar, and turtwig. If you choose the piplup, you'll have to wait for it to evolve into a prinplup, and then an empoleon. There you have it. OR you can trade something for an empoleon with your friend that has a Pokemon game in the diamond, pearl, and platinum series.
You can't catch starter Pokemon out in the common wild. If you are looking for one outside the Sinnoh region, well, in SoulSilver/HeartGold you can only get it through trading; in Black/White then you need to PokeTransfer in the PokeTransfer lab that is located just before Black City or White Forest (depending on your version ;D) you'd obviously need another Nintendo D.S. (any kind) for this and a Pokemon Pearl/Diamond/Platinum with a Piplup in there. If you need a new Piplup because yours is already evolved, wait for Lucas' sister to say where is the Ditto, catch it, put it in the Daycare with your "once-a-Piplup" and wait for the egg, there!
Im Afraid To say You cant. You Might Be Able To With A Action Replay, But You Would Have To Pick It In The Beginning. Trust Me I Went Crazy Looking For It..... Then I Looked It Up & Said Location Unknown Sorry Yes It's A Bummer
U can get piplup at da begining of da game.N u can trade it wit ur friends who haz diamond version.
the best Pokemon to pick at the start is PIPLUP or CHIMCHAR
you can't. You either have to breed one or trade with a friend.
you can't catch it because you already beaten the legendary
you can catch a lot of unknown Pokemon A-Z
gts or get a piplup and evole it
Turtwig (grass) Chimchar (fire) Piplup (water)
You cant get a piplup mask on Pokemon Diamond or Pearl u can get it but i don't know how
You cannot catch Piplup in any game.
Nowhere. You can't.
Breed your piplup with a ditto. Or breed a femle piplup with another Pokemon from the same egg group as piplup.
If you are talking about the games, Piplup was introduced in Pokemon Diamond and Pearl... Piplup was introduced in the anime Pokemon Diamond and Pearl episode 1, titled "Following a Maiden's Voyage!"
Piplup is obtained as a starter in Diamond and Pearl or through trades.
You can't catch a piplup in soulsilver
for one its Prof. Rowan and they are Piplup, Turtwig and Chimchar! hope i helped.
Piplup is a starter Pokemon if you didn't choose it have a friend trade you it.
Piplup evolves at lv. 16