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You need to have beeten the Elite 4. Then go to the statue in the middle of the Elite 4. From there you need to travel to Alder and there you will see Alder, N and Cheren. Whe you've finished talking to Alder and Cheren, you need to go up a set of stairs to N's castle. Once the gym leaders come, you'll need to go up lots of stairs until you reach a room with 2 statues of Lugia's outside. Go in there and talk to N. He will summon Reshiram and then Zekrom will lash in. Catch him with your Master Ball, then battle N. Once you beat him, Ghetsis will come and you will battle him. Once you beat him, N will release Reshiram and you will have completed Black/White.

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